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FD03725

(S)-2,5-Dihydro-3,6-dimethoxy-2-isopropylpyrazine

Chiral auxiliary used in synthesis of stereoselective α-amino acids derivatives

Technical Data

CAS No: 78342-42-4
Synonyms: (S)-Schollkopf reagent; (S)-2,5-Dimethoxy-3-isopropyl-3,6-dihydropyrazine
Product Code: FD03725
MDL No: MFCD00066229
Chemical Formula: C9H16N2O2
Molecular Weight: 184.24

Literature


  • Schöllkopf U et al (1981). Enantioselective Syntheses of (R)-Amino Acids Using L-Valine as Chiral Agent. Chem Int Ed 20(9): 798-799.
  • Schöllkopf, U (1983). Enantioselective synthesis of non-proteinogenic amino acids via metallated bis-lactim ethers of 2,5-diketopiperazines. Tetrahedron 39(12):2085-2091.
  • Kobayashi S et al (2000). Catalytic Asymmetric Strecker Synthesis. Preparation of Enantiomerically Pure α-Amino Acid Derivatives from Aldimines and Tributyltin Cyanide or Achiral Aldehydes, Amines, and Hydrogen Cyanide Using a Chiral Zirconium Catalyst. Chirality 12(5):762-766.

Solubility

Stability

Further Information


Datasheets

Specification: View
MSDS: View
Technical Bulletin: View

(S)-2,5-Dihydro-3,6-dimethoxy-2-isopropylpyrazine

CAS No:
78342-42-4
Synonyms:
(S)-Schollkopf reagent
(S)-2,5-Dimethoxy-3-isopropyl-3,6-dihydropyrazine
MDL No:
MFCD00066229
Chemical Formula:
Molecular Weight:
184.24
Product Structure
References:
1. Schöllkopf U et al (1981). Enantioselective Syntheses of (R)-Amino Acids Using L-Valine as Chiral Agent. Chem Int Ed 20(9): 798-799.
2. Schöllkopf, U (1983). Enantioselective synthesis of non-proteinogenic amino acids via metallated bis-lactim ethers of 2,5-diketopiperazines. Tetrahedron 39(12):2085-2091.
3. Kobayashi S et al (2000). Catalytic Asymmetric Strecker Synthesis. Preparation of Enantiomerically Pure α-Amino Acid Derivatives from Aldimines and Tributyltin Cyanide or Achiral Aldehydes, Amines, and Hydrogen Cyanide Using a Chiral Zirconium Catalyst. Chirality 12(5):762-766.
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